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samcastpro346crackOn-surface hydrothermal synthesis of nanoparticles with multilevel composition controlled by gas pressure and temperature. The surface-assisted synthesis of nanomaterials with precise composition is crucial to the development of nanotechnology. However, it is a challenge to prepare nano-complex structures of different compositions or structures on a surface. Herein, we present a strategy for the on-surface synthesis of gold nanoparticles with multilevel compositions by using tri-s-triazine and phenylenediamine. The hydrothermal reactions were performed in a supercritical CO2 (sc-CO2) environment under different pressures, and the reactions were completely transformed after only 90 minutes under a gas pressure of 5 MPa and a temperature of 150 °C, whereas the reaction was completed in 30 minutes under a gas pressure of 30 MPa and a temperature of 200 °C, which suggests that the reaction is more sensitive to the sc-CO2 parameters. An average size of 70 nm was obtained from the nanocomposites synthesized at different sc-CO2 pressures, and the compositions of the nanoparticles with different surface areas were analyzed by X-ray photoelectron spectroscopy (XPS), which revealed the importance of sc-CO2 pressures in the reaction process. Moreover, we propose a two-level structure model for the reaction mechanism. From this work, we developed a fast, facile and effective method for on-surface synthesis of nanomaterials with different surface areas and compositions, which can be used in the preparation of other nanomaterials with controlled compositions.David Michael Koch (born August 24, 1956), is an American businessman and philanthropist. He is a vice chairman and a major shareholder at Koch Industries. Koch’s brother Charles G. was killed in a single car accident in 1999. Koch is one of the largest funders of conservative think tanks in the United States, and a major donor to the Republican Party and many conservative organizations. In 2017, it was disclosed that Koch and his wife had given more than $1 billion to various conservative charities in the previous decade, including $300 million to the Charles Koch Foundation. Koch is one of the richest people in the U.S. and Forbes magazine once placed Koch in the “World’s Richest People” list. According to Forbes, Koch is the 185th richest person in the world. Forbes also placed him on their “All-In 37a470d65a


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