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in our view, the strength of the plasticiser is too dependent on the plasticiser/solvent ratio. indeed, with a higher plasticiser to solvent ratio, the strength of the coating is determined more by the plasticiser than the solvent. as such, the best plasticiser to solvent ratio to achieve a coating with good adhesion is not the ideal plasticiser to solvent ratio for the plasticiser-free coatings. the ideal plasticiser to solvent ratio is actually greater than unity to achieve the plasticiser-free coating.
some of the limitations of the engineering of the cement paste can be overcome by the application of a plasticiser to the cement paste. the plasticiser has two main effects on the paste. first, the plasticiser changes the state of the paste. second, the plasticiser creates a three-phase system with cement paste, water and plasticiser. the first effect is to cause the paste to be plastic. the second effect is to create a microstructure with a continuous network of microgels that give the paste greater strength. the plasticiser must be chosen carefully. the addition of a water-soluble plasticiser, such as polyethylene glycol, does not significantly affect the strength of the paste. however, there is evidence that the use of a non-water soluble plasticiser results in a higher strength cement paste, due to the greater plasticity of the paste, and a low water-to-cement ratio. the water/cement ratio should be kept as high as possible, because a higher water-to-cement ratio results in a lower setting time and a greater strength of the paste.
the use of strain or strain rate data is more often taken as a measurement of deformation, rather than a stress, and the distinction is critical because the mechanisms of deformation and stress are not the same. typically, stresses and strains are measured on different sets of test specimens and these require different approaches to determine the deformation and stress state of the materials.
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